Groundwater chemistry of the Piako catchment, Hauraki Plains
Report: TR 1993/07
Author: JC Hadfield
About this report
This study is part of a larger investigation of the Piako catchment groundwater resources.
The Piako catchment comprises an area of approximately 1435km2 of predominantly dairy farmland in the Hauraki Plains. Surface water resources in the catchment area is limited. Groundwater supplies some 80 per cent of farms and about half of the total water supply to the area.
The major content of this report is a presentation of the results from a groundwater chemistry survey undertaken in December 1992. Time series analyses are not included but are recommended for future state of environment monitoring.
Contents | ||
1 | Introduction | 1 |
2 | Hydrogeologic setting | 3 |
2.1 | Structure and geomorphology | 3 |
2.2 | Stratigraphy and formation distribution | 3 |
2.2.1 | Tauranga Group | 3 |
2.2.2 | Ignimbrites | 6 |
2.2.3 | Kiwitahi Volcanics | 7 |
2.3 | Groundwater flow regime | 7 |
3 | Sampling and data analysis | 9 |
3.1 | Sampling | 9 |
3.2 | Data analysis | 9 |
4 | Groundwater chemistry characteristics | 13 |
4.1 | Introduction | 13 |
4.2 | Groundwater chemical characteristics of geologic groupings | 15 |
4.2.1 | Hinuera Formation | 15 |
4.2.2 | Non-Hinuera Formation Tauranga Group Sediments | 18 |
4.2.3 | Ignimbrites | 19 |
4.2.4 | Kiwitahi Volcanics | 20 |
4.3 | Spatial distribution of chemical characteristics | 20 |
4.3.1 | Lateral distribution | 20 |
4.3.2 | Vertical distribution | 22 |
5 | Discussion and review of factors influencing groundwater chemistry | 29 |
5.1 | Introduction | 29 |
5.2 | Chemical influence of rainwater | 29 |
5.3 | Chemical influence of formation | 30 |
5.3.1 | Reduction and oxidation processes | 31 |
5.4 | Organic and microbial influences | 32 |
5.5 | Saltwater influence | 33 |
5.6 | Geothermal influence | 34 |
5.7 | Chemical influence on streams | 36 |
5.8 | Human influence | 36 |
6 | Environmental isotopes | 37 |
6.1 | Introduction | 37 |
6.2 | Tritium | 37 |
6.3 | Oxygen and deuterium | 38 |
7 | Groundwater quality and implications for use | 39 |
7.1 | Introduction | 39 |
7.2 | Nitrate contamination | 39 |
7.3 | Excessive iron problem | 40 |
7.4 | Domestic use | 41 |
7.5 | Agricultural use | 43 |
7.6 | Industrial use | 44 |
7.7 | Land disposal practices | 45 |
8 | Summary and conclusions | 47 |
References | 49 | |
Appendix I: Groundwater chemical analyses | 53 | |
Appendix II: Ionic ratios | 59 | |
Appendix III: Comparative box plots | 61 | |
Appendix IV: Chemistry of Hauraki Plains thermal waters | 65 |
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